Irreversible reaction

EAHQ+O₂givesC₁₆H₁₂O₂+H₂O₂

Direction: Irreversible
Processes: 1
Stated as: Fixed conversion
Heat of reaction: ΔH = -77,500 kJ/kmol (one process)
Element balance: Checked: balances

As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.

Species

Species	Name	CAS	Role	Coefficient
EAHQ	2-Ethylanthrahydroquinone	none (not merged across processes)	reactant	-1
O₂	Oxygen	7782-44-7	reactant	-1
C₁₆H₁₂O₂	2-Ethylanthraquinone	84-51-5	product	1
H₂O₂	Hydrogen peroxide	7722-84-1	product	1

In the processes

Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)Concept · not reviewed
OXDEAHQ + O2 → EAQ + H2O2
Stated as
Fixed conversion
Element balance
Balances in every element
Conversion
100 % of EAHQ (assumed: D-005: complete autoxidation of the hydroquinone in the oxidiser)
Heat of reaction
ΔH = -77,500 kJ/kmol at 298.15 K, as written (given: LVOC BREF 2017 (doi:10.2760/77304), section 12.3.4 d): 75-80 kJ/mol, midpoint)

Sources

What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.

doi:10.2760/77304
For the reaction · cited by Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)
D-005: complete autoxidation of the hydroquinone in the oxidiser
For the conversion · cited by Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)
LVOC BREF 2017 (doi:10.2760/77304), section 12.3.4 d): 75-80 kJ/mol, midpoint
For the heat of reaction · cited by Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)