Irreversible reaction

Absorption of excess NO2 in soda solution to nitrite and nitrate (side reaction)

Direction: Irreversible
Processes: 1
Stated as: Stoichiometry only
Heat of reaction: ΔH = -96,400 kJ/kmol (one process)
Element balance: Checked: balances

As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.

Species

Species	Name	CAS	Role	Coefficient
Na₂CO₃	Sodium carbonate	497-19-8	reactant	-1
NO₂	Nitrogen dioxide	10102-44-0	reactant	-2
NaNO₂	Sodium nitrite	7632-00-0	product	1
NaNO₃	Sodium nitrate	7631-99-4	product	1
CO₂	Carbon dioxide	124-38-9	product	1

In the processes

Sodium nitrite from ammonia oxidation and soda absorption (with sodium nitrate by inversion)Concept · not reviewed
NITRATE_ABS · Absorption of excess NO2 in soda solution to nitrite and nitrate (side reaction)Na2CO3 + 2 NO2 → NaNO2 + NaNO3 + CO2
Element balance
Balances in every element
Heat of reaction
ΔH = -96,400 kJ/kmol at 298.15 K, as written (assumed: D-010: NBS dHf of NaNO2(aq), NaNO3(aq) -447.48, Na2CO3(aq) (Wagman et al. 1982) with ATcT gas values, scripts/balance.py)

Sources

What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.

https://patents.google.com/patent/US2032699
For the reaction · cited by Sodium nitrite from ammonia oxidation and soda absorption (with sodium nitrate by inversion)
D-010: NBS dHf of NaNO2(aq), NaNO3(aq) -447.48, Na2CO3(aq) (Wagman et al. 1982) with ATcT gas values, scripts/balance.py
For the heat of reaction · cited by Sodium nitrite from ammonia oxidation and soda absorption (with sodium nitrate by inversion)