Irreversible reaction

CO2 reduction to CO with oxygen evolution

Direction: Irreversible
Processes: 1
Stated as: Stoichiometry only
Heat of reaction: ΔH = 565,960 kJ/kmol (one process)
Element balance: Checked: balances

As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.

Species

Species	Name	CAS	Role	Coefficient
CO₂	Carbon dioxide	124-38-9	reactant	-2
CO	Carbon monoxide	630-08-0	product	2
O₂	Oxygen	7782-44-7	product	1

Also stated as 2 CO + O2 → 2 CO2.

In the processes

CO2 electrolysis to CO in reverse-bias bipolar-membrane cells (measured bench cell, two pilot skids)Concept · not reviewed
CO2R · CO2 reduction to CO with oxygen evolutionCO2 → CO + 1/2 O2
Scale
Written at 0.5 times the scale
Element balance
Balances in every element
Heat of reaction
ΔH = 282,980 kJ/kmol at 298.15 K, as written (given: CODATA Key Values (Cox, Wagman, Medvedev 1989): dfH(CO, g) - dfH(CO2, g) = -110.53 + 393.51 kJ/mol (+- 0.21 kJ/mol))

Sources

What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.

Cox, Wagman, Medvedev, CODATA Key Values for Thermodynamics, Hemisphere, New York (1989)
For the reaction · cited by CO2 electrolysis to CO in reverse-bias bipolar-membrane cells (measured bench cell, two pilot skids)
CODATA Key Values (Cox, Wagman, Medvedev 1989): dfH(CO, g) - dfH(CO2, g) = -110.53 + 393.51 kJ/mol (+- 0.21 kJ/mol)
For the heat of reaction · cited by CO2 electrolysis to CO in reverse-bias bipolar-membrane cells (measured bench cell, two pilot skids)