Irreversible reaction

Peroxide decomposition

Direction: Irreversible
Processes: 2
Stated as: Stoichiometry only
Heat of reaction: ΔH = -196,000 kJ/kmol (one process)
Element balance: Checked: balances in all 2 processes

As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.

Species

Species	Name	CAS	Role	Coefficient
H₂O₂	Hydrogen peroxide	7722-84-1	reactant	-2
H₂O	Water	7732-18-5	product	2
O₂	Oxygen	7782-44-7	product	1

In the processes

Hydrazine hydrate by the peroxide process (PCUK, methyl ethyl ketazine route, 16 kt/a)Concept · not reviewed
DECOMP2 H2O2 → 2 H2O + O2 (unproductive peroxide decomposition)
Element balance
Balances in every element
Bleached softwood kraft pulp with chemical recovery (1000 ADt/d market pulp, concept)Concept · not reviewed
PER_DEC · Peroxide decomposition2 H2O2 → 2 H2O + O2
Element balance
Balances in every element
Heat of reaction
ΔH = -196,000 kJ/kmol at 298.15 K, as written (assumed: formation enthalpies H2O2(l) -187.8, H2O(l) -285.8 kJ/mol (NBS tables), per 2 mol H2O2)

Sources

What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.

D-004: the H2O2 not converted to azine or 2-butanol is counted as decomposed (ASSUMED pathway)
For the reaction · cited by Hydrazine hydrate by the peroxide process (PCUK, methyl ethyl ketazine route, 16 kt/a)
formation enthalpies H2O2(l) -187.8, H2O(l) -285.8 kJ/mol (NBS tables), per 2 mol H2O2
For the heat of reaction · cited by Bleached softwood kraft pulp with chemical recovery (1000 ADt/d market pulp, concept)