Irreversible reaction
Hydrolysis of o-toluenesulfonyl chloride in the quench
- Direction
- Irreversible
- Processes
- 1
- Stated as
- Rate law
- Heat of reaction
- ΔH = -60,000 kJ/kmol (one process)
- Element balance
- Checked: balances
As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.
Species
| Species | Name | CAS | Role | Coefficient |
|---|---|---|---|---|
| C7H7ClO2S | o-Toluenesulfonyl chloride | 133-59-5 | reactant | -1 |
| H2O | Water | 7732-18-5 | reactant | -1 |
| C7H8O3S | o-Toluenesulfonic acid | 88-20-0 | product | 1 |
| HCl | Hydrogen chloride | 7647-01-0 | product | 1 |
In the processes
- p-Toluenesulfonyl chloride by semi-batch chlorosulfonation of toluene with a drown-out quench (1000 t/a)Concept · not reviewed
TSHO· Hydrolysis of o-toluenesulfonyl chloride in the quencho-CH3C6H4SO2Cl + H2O → o-CH3C6H4SO3H + HCl- Stated as
- Rate law
- Phase
- liquid
- Element balance
- Balances in every element
- Heat of reaction
- ΔH = -60,000 kJ/kmol at 298.15 K, as written (assumed: ASSUMED as TSHP (D-005))
- Rate law
- basis: volume; driving: concentration; form: power_law; k: {"A":0.356,"Ea":40000}; orders: {"H2O":1,"OTSCL":1}; temperature range: 278.15 – 308.15 (assumed: ASSUMED as TSHP (D-005))
Sources
What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.
ASSUMED as TSHP
For the reaction · cited by p-Toluenesulfonyl chloride by semi-batch chlorosulfonation of toluene with a drown-out quench (1000 t/a)
ASSUMED as TSHP (D-005)
For the heat of reaction · cited by p-Toluenesulfonyl chloride by semi-batch chlorosulfonation of toluene with a drown-out quench (1000 t/a)