Formic acid 85 wt% to storage

Activity Formic acid 85 wt% by methanol carbonylation and methyl formate hydrolysis (50 kt/a), GLO: the inventory of 1 kilogram of its reference product, attributional, cut-off.

Calculation maturity: not assessed Design maturity: Concept (research)Not independently reviewedformic-acid-1:formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a:product:FAPreliminaryReport a problem with this dataset
Research outputAn inventory from a research design at the design maturity its process states, not verified plant data: check its calculation maturity and review status before use. Background activities are referenced by name only; no background data is included. All caveats

What it is

Unallocated foreground LCI of Formic acid 85 wt% by methyl formate hydrolysis (6.25 t/h, 50 kt/a), case design, derived from the flowsheet by cheme assess lca.

Reference product
1 kilogram of Formic acid 85 wt% to storage (liquid, 0.12 bar(a), 44.85 degC, 68.9251 % FA (mole))
Chemical
formic-acid
CAS
64-18-6
Code
formic-acid-1:formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a:product:FA
Dataset
formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a version 0.1.0 · UUID 8f7fd603-106e-54ec-976e-b882a7cd9cc3
Activity UUID
not available (the library assigns none; use the code)
Database
cheme-as-code-atlas-preview-c3ab348 (version preview-c3ab348)
Process
Formic acid 85 wt% by methanol carbonylation and methyl formate hydrolysis (50 kt/a)
Geography
GLO · background inputs with a site rule link at the user's site location (default DE)
Time period
2026 · valid until 2031
Technology
Methanol carbonylation over sodium methoxide (353 K, 4.5 MPa), methyl formate hydrolysis autocatalysed by formic acid (393 K), methyl formate and methanol recycle, pressure-swing distillation (203 / 12 kPa(a)) to 85 wt%; CO-rich vent burnt; 6.25 t/h · level current
Boundary
gate-to-gate foreground of the plant
Production volume
50,000,000 kg/a (product:FA per hour x operation.hours_per_year (8000 h/a))
Classification
ISIC Rev.4 2011 (taxonomy/families.yaml (ISIC Rev.4) of the process's families)
System model
attributional, cut-off (docs/system-model.md, methodology 1.1.0)
Allocation
mass, 100 % of the dataset to this product (rule single-output, from default)
one product: nothing to allocate
Rights
CC-BY-4.0: the ChemE-as-Code process library's own concept design (LICENSE-DATA)

Exchanges per 1 kilogram of Formic acid 85 wt% to storage

As exported: allocated and scaled to the reference product. Provenance: 7 assumed, 5 calculated. Pedigree scores (1 best, 5 worst): reliability, completeness, temporal correlation, geographical correlation, further technological correlation.

Preliminary4 exchanges are not yet linked to a background dataset. They count no burden, so the inventory is incomplete: do not read a result from it as complete.
InputAmountUnitProvenancePedigreeLinked to
Carbon monoxide (from a syngas cold box outside the boundary)
feed:CO
flowsheet stream S1 (scripts/balance.py, D-003, D-005)
From stream S1
0.5685kilogramassumed4 4 1 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Methanol make-up (methanol-1)
feed:MEOH
flowsheet stream S3 (D-003, D-007): make-up for the methanol lost with the purge and the vent
From stream S3
0.01246kilogramassumed4 4 1 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Sodium methoxide 30 wt% in methanol
feed:CAT
flowsheet stream S4 (D-007): methoxide destroyed by water plus purged
From stream S4
0.002319kilogramassumed4 4 1 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Process water (demineralised)
feed:PW
flowsheet stream S17 (D-008)
From stream S17
0.4828kilogramassumed4 4 1 3 3market for water, deionised (water, deionised, RoW) in your background (default ecoinvent-3.11-cutoff)
Electric power
feed:POWER
flowsheet energy streams Q1 (CO compressor), Q3, Q8 (pumps), Q19 (vacuum system), D-010, D-011
electricity
From streams Q1, Q3, Q8, Q19
0.0843kilowatt hourassumed4 4 1 3 3market for electricity, medium voltage (electricity, medium voltage, DE, site location) in your background (default ecoinvent-3.11-cutoff)
Low-pressure steam (450 kPa(a), saturated)
feed:LPS
flowsheet energy streams Q6, Q9, Q10, Q11, Q13, Q15, Q17 (reboilers, feed preheater, hydrolyser), D-011
steam, LP, 147.65 degC, 4.5 bar(a)
From streams Q6, Q9, Q10, Q11, Q13, Q15, Q17
4.463kilowatt hourassumed4 4 1 3 3Atlas: heat from steam, per kWh (Atlas unit proxy) (heat from steam, by energy, GLO)
Spent catalyst purge (sodium formate and methoxide in methanol) to incineration
product:PURGE
flowsheet stream S14 (D-007)
From stream S14
0.0141kilogramcalculated3 4 1 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Cooling water return
product:CW
flowsheet energy streams Q2, Q4, Q5, Q7, Q12, Q14, Q16, Q18, D-011
cold, 25 degC
From streams Q2, Q4, Q5, Q7, Q12, Q14, Q16, Q18
4.488kilowatt hourassumed4 4 1 3 3Atlas (plant): cooling water service, per kWh heat rejected (Atlas screening proxy) (heat rejected to cooling water, GLO)
compatible: grade the input names cooling-water only; cooling-water (Heat rejected to cooling water, 25/35 degC) is taken; unit kilowatt hour; carrier cold, 25 degC from cold, 25 degC; system model cutoff (one database); allocation mass (single-output); boundary plant gate of a site utility: no utility market yet (docs/markets.md)

Elementary flows

FlowDirectionCompartmentAmountUnitProvenancePedigree
Carbon monoxide, fossil
099b36ab-4c03-4587-87f4-2f81e337afb8
From stream S16
emissionair / non-urban air or from high stacks4.492e-5kilogramcalculated3 4 1 3 3
Carbon dioxide, fossil
aa7cac3a-3625-41d4-bc54-33e2cf11ec46
From stream S16
emissionair / non-urban air or from high stacks0.07239kilogramcalculated3 4 1 3 3
Methanol
0ebdb68a-f50d-4b0c-ad4b-3a1104d8b454
From stream S16
emissionair3.179e-7kilogramcalculated3 4 1 3 3
Methyl formate
4877b7b5-0ac1-47f7-96bd-677179544c9f
From stream S16
emissionair9.821e-7kilogramcalculated3 4 1 3 3

The streams are the plant's own flows: an amount here is allocated and per 1 kilogram of Formic acid 85 wt% to storage, so it differs from the stream's flow, and it can sum several streams.

Where these numbers come from: each exchange names its source above; the dataset is processes/formic-acid-1/lca/dataset.yaml in library version c3ab348.

Used by

No other activity of this database links to it.

How good it is

Review
Not reviewed: no LCI review record yet
Data quality
DQR 2.33 · PEF-style DQR 2.5
TeR 3 · GeR 3 · TiR 1 · P 3 · C 4 · weakest TeR · primary data 0 %
Mass and carbon closure
Assessed (lca/manifest.json balance, tolerance 5 %: design maturity concept (sourced screening))
  • lci-carbon-origin: closed
  • lci-element-balance: closed
  • lci-mass-balance: closed
Change report
Not available: this build has no change report against an earlier release.

KPI benchmark positions

Not available: no benchmarked KPI for this dataset.

How to use it

Downloads

A file with this activity alone is not available: each file above is the whole database, and the line under it says how to find this activity there.

import bw2data as bd
from cheme_as_code_lci import install

bd.projects.set_current("my-project")   # holds your licensed background + biosphere3
install("cheme-as-code-atlas-preview-c3ab348.xlsx", background="ecoinvent-3.11-cutoff", location="DE")
activity = bd.get_activity(("cheme-as-code-atlas-preview-c3ab348", "formic-acid-1:formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a:product:FA"))

While any exchange of the database has no mapping, install() writes nothing and only lists the unlinked exchanges. So the last line finds no activity until the gaps are mapped: the download section gives the ways to use the database now.

How to cite

Formic acid 85 wt% to storage, from Formic acid 85 wt% by methanol carbonylation and methyl formate hydrolysis (50 kt/a) (dataset formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a 0.1.0), ChemE-as-Code Process Atlas LCI database preview-c3ab348, activity formic-acid-1:formic-acid-85-wt-by-methyl-formate-hydrolysis-6.25-t-h-50-kt-a:product:FA. Cite the Process Atlas paper (in preparation, 2026), by Artur M. Schweidtmann and Jana M. Weber, and the ChemE-as-Code Process Atlas LCI database version preview-c3ab348.

DOI: none yet (the Process Atlas paper is in preparation)

For the data, cite the Process Atlas paper; for the platform that builds and checks it, the ChemE-as-Code paper.

Schweidtmann, A. M. & Weber, J. M. (2026, in preparation). Process Atlas: an open, git-native, reproducible library and life cycle inventory of chemical processes (working title).

BibTeX
@unpublished{schweidtmann_process_atlas,
  author = {Schweidtmann, Artur M. and Weber, Jana M.},
  title = {{Process Atlas: an open, git-native, reproducible library and life cycle inventory of chemical processes (working title)}},
  year = {2026},
  url = {https://atlas.cheme-as-code.org},
  note = {in preparation}
}

Schweidtmann, A. M. (2026, in preparation). ChemE-as-Code: An Open-Source Platform for AI-Accelerated Chemical Process Engineering (working title).

BibTeX
@unpublished{schweidtmann_cheme_as_code,
  author = {Schweidtmann, Artur M.},
  title = {{ChemE-as-Code: An Open-Source Platform for AI-Accelerated Chemical Process Engineering (working title)}},
  year = {2026},
  url = {https://cheme-as-code.org},
  note = {in preparation}
}