Refinery fuel gas, C1-C2 gas to the refinery fuel system (after amine treating)

Activity Hydrocracking of vacuum gas oil, single-stage recycle, RER: the inventory of 1 kilogram of its reference product, attributional, cut-off.

Calculation maturity: not assessed Design maturity: Concept (research)Not independently reviewedhydrocracking-1:hydrocracking-vgo-single-stage-recycle:product:fuel-gasPreliminaryReport a problem with this dataset
Research outputAn inventory from a research design at the design maturity its process states, not verified plant data: check its calculation maturity and review status before use. Background activities are referenced by name only; no background data is included. All caveats

What it is

Per 1 t of hydrocracked products (LPG to diesel range, unsplit), gate-to-gate, from the EU REF BREF ranges. Fresh vacuum gas oil and hydrogen on a fixed-bed catalyst at high pressure, with recycle of the unconverted oil to 97 to 98 % conversion. The C1-C2 gas and the unconverted-oil bleed are co-products.

Reference product
1 kilogram of Refinery fuel gas, C1-C2 gas to the refinery fuel system (after amine treating)
Chemical
refinery-fuel-gas
CAS
not available
Code
hydrocracking-1:hydrocracking-vgo-single-stage-recycle:product:fuel-gas
Dataset
hydrocracking-vgo-single-stage-recycle version 0.1.0 · UUID 7bffe138-3bbc-5c3a-9755-82b7c16fe4d2
Activity UUID
not available (the library assigns none; use the code)
Database
cheme-as-code-atlas-preview-a3c52e4 (version preview-a3c52e4)
Process
Hydrocracking of vacuum gas oil, single-stage recycle
Geography
RER · background inputs with a site rule link at the user's site location (default DE)
Time period
1991 · valid until 2004
Technology
high-pressure fixed-bed hydrocracking (100 to 200 barg, 340 to 425 degC, REF BREF Table 2.9), single-stage with recycle of the unconverted oil; once-through, two-stage, mild and residue hydrocracking are not modelled · level current
Boundary
gate-to-gate: feed heater, reactors, HP and LP separators, fractionation; hydrogen, fuel and power from outside; amine treating, sulfur recovery and sour water stripping outside
Classification
ISIC Rev.4 1920 (taxonomy/families.yaml (ISIC Rev.4) of the process's families)
System model
attributional, cut-off (docs/system-model.md, methodology 1.1.0)
Allocation
energy, 1.1 % of the dataset to this product (rule physical-energy, from mappings)
The hydrocracked products, the C1-C2 gas and the unconverted-oil bleed are fuels and fuel blendstocks, so energy content (LHV) is the physical relationship (hierarchy step 2). LHVs are IPCC 2006 defaults per cut, the unsplit product's ASSUMED (jet kerosene), given in the dataset.
Rights
CC-BY-4.0

Exchanges per 1 kilogram of Refinery fuel gas, C1-C2 gas to the refinery fuel system (after amine treating)

As exported: allocated and scaled to the reference product. Provenance: 12 calculated, 2 assumed. Pedigree scores (1 best, 5 worst): reliability, completeness, temporal correlation, geographical correlation, further technological correlation.

Preliminary4 exchanges are not yet linked to a background dataset. They count no burden, so the inventory is incomplete: do not read a result from it as complete.
InputAmountUnitProvenancePedigreeLinked to
Vacuum gas oil, fresh feed (about 1.0 % S w/w)
feed:vacuum-gas-oil
carbon balance over the surrogates: the feed whose carbon leaves as the product, the C1-C2 gas and the bleed. Feed modelled as C225H395S (ASSUMED): 1.02 % S w/w, the sulfur of the linked crude's vacuum gas oil (TotalEnergies crude oil data sheet Johan Sverdrup (assay of 01-Apr-2021, sheet Jul-21, manufacturer literature; the sheet gives no guarantee of accuracy), properties of TBP cuts, vacuum distillate 375 to 565 degC: 1.00 wt% S, 931 kg/m3, UOP K 11.8), and 12.7 % H w/w (ASSUMED, a typical VGO; the assay gives no hydrogen). The REF BREF's hydrocracker feeds of Table 3.62 carry 2 to 3 % S. Feed nitrogen is not modelled (TODO)
1.102kilogramcalculated4 4 4 4 4Atlas (pinned): Crude oil distillation, atmospheric and vacuum (crude and high vacuum units) (Vacuum gas oil (360 to 560 degC, light and heavy), RER)
compatible: grade the input names vacuum-gas-oil only; vacuum-gas-oil (Vacuum gas oil (360 to 560 degC, light and heavy)) is taken; unit kilogram; system model cutoff (one database); allocation energy (physical-energy); boundary plant gate (pinned): no distribution or losses; the consumer's dataset counts its delivery
Hydrogen, chemical consumption
feed:hydrogen
REF BREF Table 3.62, p. 192 (midpoint of 260 to 400 Nm3/t, chemical consumption) at 0 degC and 101.325 kPa; make-up for solution and purge losses not included (TODO)
0.0327kilogramcalculated3 4 5 3 3Atlas (pinned): Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export) (Hydrogen product 99.9 mol% to battery limit, GLO)
compatible: grade the input names hydrogen only; hydrogen (Hydrogen product 99.9 mol% to battery limit) is taken; unit kilogram; system model cutoff (one database); allocation exergy (deviation); boundary plant gate (pinned): no distribution or losses; the consumer's dataset counts its delivery
Fuel to the reactor and fractionator heaters (as natural gas, methane)
feed:natural-gas
REF BREF Table 3.66, p. 195 (fuel 400 to 1200 MJ/t, midpoint, read as LHV) over the LHV of methane; a refinery fires mostly its own fuel gas, natural gas is the proxy (ASSUMED)
fuel, LHV 50.01 MJ/kg
0.01762kilogramcalculated3 4 5 3 3Atlas: natural gas, per kg, as methane (Atlas unit proxy) (natural gas, by mass, GLO)
Wash water to the reactor effluent
feed:water
ASSUMED equal to the sour water, so that the water balance closes
0.08814kilogramassumed4 4 4 4 4market for water, deionised (water, deionised, RoW) in your background (default ecoinvent-3.11-cutoff)
Electricity
feed:electricity
REF BREF Table 3.66, p. 195 (20 to 150 kWh/t of feed, midpoint) per t of feed
electricity
0.09364kilowatt hourcalculated3 4 5 3 3market for electricity, medium voltage (electricity, medium voltage, DE, site location) in your background (default ecoinvent-3.11-cutoff)
Hydrocracking catalyst (Ni, Mo, Co or W oxides on alumina, silica-alumina or zeolite)
input:catalyst
REF BREF section 3.13.2, p. 195 (57.4 t per Mt of feedstock, average), taken as the make-up; mass outside the element balance
6.324e-5kilogramcalculated3 4 5 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Spent hydrocracking catalyst (to regeneration or metals recovery)
output:spent-catalyst
REF BREF section 3.13.2, p. 195 (spent catalyst fines with metals from the crude and hydrocarbons; supplier take-back for regeneration is common, p. 194); taken equal to the make-up; mass outside the element balance
6.324e-5kilogramcalculated3 4 5 3 3unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Hydrogen sulfide in the sour gas, to amine treating and sulfur recovery
output:H2S
all feed sulfur leaves as H2S (the products are practically sulfur-free, REF BREF section 2.13, p. 80); the share dissolved in the sour water is counted here too (ASSUMED)
0.01198kilogramcalculated4 4 4 4 4unlinked
unlinked, no technosphere mapping: no mapping (chemical 'hydrogen-sulfide'); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Hydrogen balance residual, to the refinery fuel gas
output:offgas
closes the hydrogen balance of the surrogates with the sourced consumption; near zero by the choice of surrogates (README, What is weak); not a measured purge
6.166e-4kilogramassumed4 4 4 4 4unlinked
unlinked, no technosphere mapping: no mapping (no chemical slug or factor id); add it to lci/mappings.yaml technosphere or to the process's lca/mappings.yaml exchanges
Sour water, to the sour water stripper and wastewater treatment
output:wastewater
REF BREF section 3.13.2, p. 195 (50 to 110 l/t, midpoint, taken at 1 kg/l); high COD, H2S, NH3; its H2S and NH3 are not counted here (TODO)
0.08814kilogramcalculated3 4 5 3 3Atlas (plant): wastewater to treatment, per kg (Atlas unit proxy) (wastewater, by mass, GLO)
compatible: grade the input names wastewater only; wastewater (Wastewater treated) is taken; unit kilogram; system model cutoff (one database); allocation mass (single-output); boundary plant gate of a site utility: no utility market yet (docs/markets.md)

Elementary flows

FlowDirectionCompartmentAmountUnitProvenancePedigree
Carbon dioxide, fossil
349b29d1-3e58-4c66-98b9-9d1a076efd2e
emissionair0.04834kilogramcalculated3 4 5 3 3
Water
075e433b-4be4-448e-9510-9a5029c1ce94
emissionair3.958e-5cubic metercalculated3 4 5 3 3
Methane, fossil
0795345f-c7ae-410c-ad25-1845784c75f5
emissionair8.814e-7kilogramcalculated4 4 4 4 4
Dinitrogen monoxide
20185046-64bb-4c09-a8e7-e8a9e144ca98
emissionair8.814e-8kilogramcalculated4 4 4 4 4

Where these numbers come from: each exchange names its source above; the dataset is processes/hydrocracking-1/lca/datasets/hydrocracking-vgo-single-stage-recycle.yaml in library version a3c52e4.

Used by

No other activity of this database links to it.

How good it is

Review
Not reviewed: no LCI review record yet
Data quality
not available
Mass and carbon closure
Not available: a hand-written dataset: no lca/manifest.json records its balance
Change report
Not available: this build has no change report against an earlier release.

KPI benchmark positions

KPIValueReference rangePosition
Hydrogen chemically consumed per t of fresh feed, vacuum gas oil hydrocracking
No open per-mass range independent of the dataset found (2026-11-05). The REF BREF range (Table 3.62, 260 to 400 Nm3/t) is the dataset's own source. Per-barrel figures (US DOE 1998, Energetics, section 4.1.4: 1000 to 2500 scf/bbl) need a feed density to become kg/t, a modelling step. Searched: open reviews and course notes on VGO hydrocracking (only scf/bbl or single pilot-test values, e.g. Peng et al. 2018, Front. Chem. Sci. Eng. 12:867).
– kg/tnot availablenot evaluated
Sour water per t of fresh feed, hydrocracking
No open range independent of the dataset found (2026-11-05). The REF BREF range (section 3.13.2, 50 to 110 l/t) is the dataset's own source; no other open source read for this entry states a hydrocracker waste-water flow.
– kg/tnot availablenot evaluated
Electricity per t of fresh feed, hydrocracking
No open range independent of the dataset found (2026-11-05). The REF BREF range (Table 3.66, 20 to 150 kWh/t, after Sema, Sofres 1991 and VROM 1999) is the dataset's own source. Read and not usable: US DOE 1998 (Energetics, Table 4-8, per bbl), DOE 2006 Energy Bandwidth (no hydrocracking section), PRELIM v1.5 documentation (no values printed).
– kWh/tnot availablenot evaluated

How to use it

Downloads

A file with this activity alone is not available: each file above is the whole database, and the line under it says how to find this activity there.

import bw2data as bd
from cheme_as_code_lci import install

bd.projects.set_current("my-project")   # holds your licensed background + biosphere3
install("cheme-as-code-atlas-preview-a3c52e4.xlsx", background="ecoinvent-3.11-cutoff", location="DE")
activity = bd.get_activity(("cheme-as-code-atlas-preview-a3c52e4", "hydrocracking-1:hydrocracking-vgo-single-stage-recycle:product:fuel-gas"))

While any exchange of the database has no mapping, install() writes nothing and only lists the unlinked exchanges. So the last line finds no activity until the gaps are mapped: the download section gives the ways to use the database now.

How to cite

Refinery fuel gas, C1-C2 gas to the refinery fuel system (after amine treating), from Hydrocracking of vacuum gas oil, single-stage recycle (dataset hydrocracking-vgo-single-stage-recycle 0.1.0), ChemE-as-Code Process Atlas LCI database preview-a3c52e4, activity hydrocracking-1:hydrocracking-vgo-single-stage-recycle:product:fuel-gas. Cite the Process Atlas paper (in preparation, 2026), by Artur M. Schweidtmann and Jana M. Weber, and the ChemE-as-Code Process Atlas LCI database version preview-a3c52e4.

DOI: none yet (the Process Atlas paper is in preparation)

For the data, cite the Process Atlas paper; for the platform that builds and checks it, the ChemE-as-Code paper.

Schweidtmann, A. M. & Weber, J. M. (2026, in preparation). Process Atlas: an open, git-native, reproducible library and life cycle inventory of chemical processes (working title).

BibTeX
@unpublished{schweidtmann_process_atlas,
  author = {Schweidtmann, Artur M. and Weber, Jana M.},
  title = {{Process Atlas: an open, git-native, reproducible library and life cycle inventory of chemical processes (working title)}},
  year = {2026},
  url = {https://atlas.cheme-as-code.org},
  note = {in preparation}
}

Schweidtmann, A. M. (2026). ChemE-as-Code: An Open-Source Platform for Agentic AI in Chemical Engineering. arXiv:2611.07947. https://doi.org/10.48550/arXiv.2611.07947

BibTeX
@misc{schweidtmann_cheme_as_code,
  author = {Schweidtmann, Artur M.},
  title = {{ChemE-as-Code: An Open-Source Platform for Agentic AI in Chemical Engineering}},
  year = {2026},
  eprint = {2611.07947},
  archivePrefix = {arXiv},
  doi = {10.48550/arXiv.2611.07947},
  url = {https://arxiv.org/abs/2611.07947}
}