Irreversible reaction
COCl2+H2OgivesCO2+2HCl
- Direction
- Irreversible
- Processes
- 1
- Stated as
- Fixed conversion
- Heat of reaction
- ΔH = -116,968 kJ/kmol (one process)
- Element balance
- Checked: balances
As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.
Species
| Species | Name | CAS | Role | Coefficient |
|---|---|---|---|---|
| COCl2 | Phosgene | 75-44-5 | reactant | -1 |
| H2O | Water | 7732-18-5 | reactant | -1 |
| CO2 | Carbon dioxide | 124-38-9 | product | 1 |
| HCl | Hydrogen chloride | 7647-01-0 | product | 2 |
In the processes
- Phosgene from CO and chlorine over activated carbon (17.3 t/h liquid phosgene, captive)Concept · not reviewed
PHOS_HYDCOCl2 + H2O → CO2 + 2 HCl- Stated as
- Fixed conversion
- Element balance
- Balances in every element
- Conversion
- 99 % of
COCL2(assumed: D-009: residual phosgene hydrolysed in the oxidiser at 1123 K, ASSUMED) - Heat of reaction
- ΔH = -116,968 kJ/kmol at 298.15 K, as written (given: ideal-gas formation enthalpies of materials.yaml (ATcT), 298.15 K)
Sources
What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.
D-009: residual phosgene hydrolysed in the oxidiser at 1123 K, ASSUMED
For the conversion · cited by Phosgene from CO and chlorine over activated carbon (17.3 t/h liquid phosgene, captive)
ideal-gas formation enthalpies of materials.yaml (ATcT), 298.15 K
For the heat of reaction · cited by Phosgene from CO and chlorine over activated carbon (17.3 t/h liquid phosgene, captive)