Irreversible reaction
H2O2+H2gives2H2O
- Direction
- Irreversible
- Processes
- 1
- Stated as
- Fixed conversion
- Heat of reaction
- ΔH = -383,880 kJ/kmol (one process)
- Element balance
- Checked: balances
As the processes state itStoichiometry, conversions, heats of reaction and catalyst windows are taken from each process's files with their provenance. The build checks only that each process's equation balances in every element, from the process's own component formulas; it does not check the numbers. A process's design maturity applies to them.
Species
In the processes
- Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)Concept · not reviewed
HPDH2O2 + H2 → 2 H2O- Stated as
- Fixed conversion
- Element balance
- Balances in every element
- Conversion
- 100 % of
H2O2(assumed: D-005: residual H2O2 in the recycled WS is destroyed on the Pd catalyst) - Heat of reaction
- ΔH = -383,880 kJ/kmol at 298.15 K, as written (given: standard enthalpies of formation, liquid H2O2 and water, 298 K (NIST Chemistry WebBook))
- Catalyst
- Pd on alumina, fixed bed (D-003)
Sources
What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.
D-005: residual H2O2 in the recycled WS is destroyed on the Pd catalyst
For the conversion · cited by Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)
standard enthalpies of formation, liquid H2O2 and water, 298 K (NIST Chemistry WebBook)
For the heat of reaction · cited by Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)