substance
Hydrogen
- Formula
- H2
- CAS
- 1333-74-0
- InChIKey
- UFHFLCQGNIYNRP-UHFFFAOYSA-N
- ChEBI
- CHEBI:18276
Made by
- Chlor-alkali by membrane-cell electrolysis (100 kt/a Cl2, 50 wt-% caustic soda, hydrogen)Co-productConcept · not reviewed
- Toluene hydrodealkylation to benzene (100 kt/a, thermal HDA)Co-productConcept · not reviewed
- Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export)Main productConcept · not reviewed
Used by
- Acetic acid by low-water iridium methanol carbonylation (60 t/h glacial acid, concept)ReactantConcept · not reviewed
- Acetone and phenol from cumene (cumene hydroperoxide route, 200 kt/a phenol)ReactantConcept · not reviewed
- Aniline by adiabatic gas-phase hydrogenation of nitrobenzene (25 t/h)FeedstockConcept · not reviewed
- N,N-Dimethylformamide by carbonylation of dimethylamine (50 kt/a, sodium methoxide in methanol)FeedstockConcept · not reviewed
- Toluene hydrodealkylation to benzene (100 kt/a, thermal HDA)FeedstockConcept · not reviewed
- Hydrogen bromide synthesis burner with catalytic finishing and absorption (48 wt-% hydrobromic acid)FeedstockConcept · not reviewed
- Hydrogen chloride synthesis burner and absorption (33 wt-% hydrochloric acid, steam recovery)FeedstockConcept · not reviewed
- Hydrogen peroxide by the anthraquinone autoxidation process (50 kt/a H2O2, 50 wt%)FeedstockConcept · not reviewed
- Hydroxylammonium sulfate by catalytic NO hydrogenation (30 kt/a NH2OH, 25 wt% solution)FeedstockConcept · not reviewed
- Methanol synthesis loop and purification (2500 t/d Grade AA, natural-gas syngas)FeedstockConcept · not reviewed
Emitted by
- Hydrogen bromide synthesis burner with catalytic finishing and absorption (48 wt-% hydrobromic acid)EmissionConcept · not reviewed
- Hydrogen chloride synthesis burner and absorption (33 wt-% hydrochloric acid, steam recovery)EmissionConcept · not reviewed
- Potassium permanganate from MnO2 ore by KOH roasting and electrolysis (1250 kg/h, concept)EmissionConcept · not reviewed
Takes part in
- 2C2H6givesC4H10+H2Product · one process
- 2C2H6givesC4H6+3H2Product · one process
- 2C2H6givesC4H8+2H2Product · one process
- 2C6H5NO2+6H2givesC12H11N+NH3+4H2OReactant · one process
- 2C6H6in equilibrium withC12H10+H2Product · one process
- 2CH4+O2gives2CO+4H2Product · one process
- 2CH4givesC2H2+3H2Product · one process
- C2H6+2H2Oin equilibrium with2CO+5H2Product · one process
- 2H2+O2in equilibrium with2H2OReactant · Combustion of the oxygen in the chlorine feed with excess hydrogen · one process
- 2H2+O2gives2H2OReactant · 6 processes
- 2K2MnO4+2H2Ogives2KMnO4+2KOH+H2Product · Anodic oxidation of manganate to permanganate (overall cell reaction) · one process
- 2NaCl+2H2OgivesCl2+H2+2NaOHProduct · Chlor-alkali electrolysis (overall cell reaction) · one process
- 2H2Ogives2H2+O2Product · Anodic oxygen from back-migrated hydroxide (net water electrolysis) · 2 processes
- H2+Br2in equilibrium with2HBrReactant · Hydrogen bromide synthesis (bromine vapour burnt in hydrogen) · one process
- H2+Cl2in equilibrium with2HClReactant · Hydrogen chloride synthesis (chlorine burnt in hydrogen) · one process
- N2+3H2in equilibrium with2NH3Reactant · one process
- 2NH3givesN2+3H2Product · one process
- 3C2H6gives2C3H4+5H2Product · one process
- 3C2H6gives2C3H6+3H2Product · one process
- 3C2H6gives2C3H8+H2Product · one process
- 3C2H6givesC6H6+6H2Product · one process
- C3H8+3H2Oin equilibrium with3CO+7H2Product · one process
- 2NO+3H2+H2SO4givesH8N2O6SReactant · one process
- 4CH4givesC4H2+7H2Product · one process
- 2NO+5H2+H2SO4givesH8N2O4S+2H2OReactant · one process
- 6CH4givesC6H6+9H2Product · one process
- C16H12O2+H2givesEAHQReactant · one process
- C2H2+2H2givesC2H6Reactant · one process
- C2H2+H2givesC2H4Reactant · one process
- C2H6in equilibrium withC2H4+H2Product · one process
- C2H4O2+CO+2H2givesC3H6O2+H2OReactant · one process
- C2H6+2H2Ogives2CO+5H2Product · one process
- C2H6+H2gives2CH4Reactant · one process
- C2H6givesC2H2+2H2Product · one process
- C3H4+2H2givesC3H8Reactant · one process
- C3H4+H2givesC3H6Reactant · one process
- C3H8+3H2Ogives3CO+7H2Product · one process
- C3H8+H2givesC2H6+CH4Reactant · one process
- C3H8givesC3H6+H2Product · one process
- C6H5NO2+3H2givesC6H7N+2H2OReactant · one process
- C6H5NO2+4H2givesC6H6+NH3+2H2OReactant · one process
- C7H8+H2givesC6H6+CH4Reactant · one process
- C9H10+H2givesC9H12Reactant · one process
- CH4+H2Oin equilibrium withCO+3H2Product · 2 processes
- CH4+H2OgivesCO+3H2Product · one process
- CH4givesC+2H2Product · one process
- CO+2H2in equilibrium withCH4OReactant · one process
- CH4O+H2givesCH4+H2OReactant · one process
- CO2+3H2in equilibrium withCH4O+H2OReactant · one process
- CO+3H2givesCH4+H2OReactant · one process
- CO+H2Oin equilibrium withCO2+H2Product · 3 processes
- CO+H2OgivesCO2+H2Product · one process
- CO2+4H2givesCH4+2H2OReactant · one process
- 2NO+H2givesN2O+H2OReactant · one process
- H2O2+H2gives2H2OReactant · one process
Routes compared
All 3 ways to make Hydrogen, with filters →
Not comparable as they standAllocation: differs; Reference product (grade, state): differs. The rows say which route each warning concerns.
Per 1 kg of Hydrogen: inventory from each route's LCI dataset, unallocated; footprints per the functional unit of their own LCA.
| Route | Tier, design maturity, review status | Geography, year | Energy | Feedstocks | Key emissions | Footprint | Comparability |
|---|---|---|---|---|---|---|---|
| Chlor-alkali by membrane-cell electrolysis (100 kt/a Cl2, 50 wt-% caustic soda, hydrogen)bipolar membrane-cell NaCl electrolysis, 100 kt/a Cl2, rock salt with brine recirculation, 3.0 V at 6.0 kA/m2, double-effect caustic evaporation to 50 wt-% | flowsheet or hand-writtenDesign maturity: Concept (research)Not independently reviewedDataset review: unreviewed | GLO, 2026 | a co-product of a multi-output dataset (product:CL2, product:NAOH besides it): its share needs the allocation of the LCI database build | no footprint |
| ||
| Toluene hydrodealkylation to benzene (100 kt/a, thermal HDA)thermal toluene hydrodealkylation, adiabatic reactor 895-936 K / 3.4 MPa, H2 recycle with purge and purge hydrogen recovery by PSA, stabiliser, benzene and vacuum toluene columns; 100 kt/a benzene, concept design | flowsheet or hand-writtenDesign maturity: Concept (research)Not independently reviewedDataset review: unreviewed | GLO, 2026 | a co-product of a multi-output dataset (product:BENZENE, product:DIPHENYL besides it): its share needs the allocation of the LCI database build | no footprint |
| ||
| Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export)natural-gas steam methane reforming, top-fired tubular reformer, HT shift, hydrogen PSA, tail gas firing, steam export; 100 000 Nm3/h | flowsheet or hand-writtenDesign maturity: Concept (research)Not independently reviewedDataset review: unreviewed | generic, 2026 |
|
|
| 9.14 kg CO2-eqClimate change per 1 kg hydrogen |
|
How comparability is checked
- Allocation
- differs (same allocation method: energy, exergy, shares)
- Background data (impacts)
- not applicable (same background data and boundary behind the impact numbers (only routes with a footprint))
- System boundary
- same (same system boundary of the inventory (the dataset's boundary): gate-to-gate foreground of the plant)
- Data quality (TfS DQR)
- same (data quality: every route states a TfS DQR, none more than 1 above the best)
- Functional unit
- same (same functional unit (amount and unit of the reference product): 1 kg)
- Reference product (grade, state)
- differs (same reference product: registry grade and state: no grade (basis mass, component H2, pressure 1.4, purity 0.6789415, temperature 64.04), no grade (basis mole, component H2, pressure 28.5, purity 0.998996, temperature 40.0), no grade (temperature 40.0))
- System model
- same (same system model (docs/system-model.md): cutoff)
ISO 14044 requires a critical review (by a panel of interested parties, ISO/TS 14071) of a comparative assertion intended to be disclosed to the public. These routes are listed side by side for screening; a statement that one is better than another needs that review. None of these routes has had such a review.