CO+H₂O⇌in equilibrium withCO₂+H₂

Species

Also stated as CO + H2O → CO2 + H2 (reversible and irreversible statements are kept apart).

In the processes

• Ammonia from natural gas (1500 t/d, steam reforming with air-fed secondary reformer, Haber-Bosch loop)Concept · not reviewed

  WGSCO + H2O ⇌ CO2 + H2

  Stated as

  Equilibrium

  Element balance

  Balances in every element

• Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export)Concept · not reviewed

  WGSCO + H2O ⇌ CO2 + H2

  Stated as

  Equilibrium

  Element balance

  Balances in every element

  Heat of reaction

  ΔH = -41,127 kJ/kmol at 298.15 K, as written (given: standard formation enthalpies, 298.15 K (process/materials.yaml))

• Methanol synthesis loop and purification (2500 t/d Grade AA, natural-gas syngas)Concept · not reviewed

  WGSCO + H2O ⇌ CO2 + H2

  Stated as

  Equilibrium

  Element balance

  Balances in every element

  Heat of reaction

  ΔH = -41,200 kJ/kmol at 298.15 K, as written (given: standard enthalpies of formation, 298 K)

Sources

What the processes cite for this reaction, each source once: for the reaction itself, its conversion, its heat of reaction or its catalyst. As the processes write them; DOIs, US patent numbers and web addresses are linked.

1. cheme reaction library steam_reforming, ht_shift, lt_shift

   For the reaction · cited by Ammonia from natural gas (1500 t/d, steam reforming with air-fed secondary reformer, Haber-Bosch loop)

2. cheme chemistry library steam_reforming, ht_shift (Twigg, Catalyst Handbook, 2nd ed., 1989)

   For the reaction · cited by Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export)

3. standard formation enthalpies, 298.15 K (process/materials.yaml)

   For the heat of reaction · cited by Hydrogen by natural-gas steam methane reforming with PSA (100 000 Nm3/h, steam export)

4. standard enthalpies of formation, 298 K

   For the heat of reaction · cited by Methanol synthesis loop and purification (2500 t/d Grade AA, natural-gas syngas)

Starter template

Templates bring the stoichiometry, the components and typical catalysts; most give no conversion or kinetics, and their sources are general references, not this reaction's processes.