The case starts from the experiments of Prats Vergel, Vermaas, Burdyny and colleagues (Nature Chemical Engineering 2025; 4TU dataset v1, CC BY 4.0). A 5 cm2 membrane electrode assembly reduces humidified CO2 to CO and H2 at a silver gas-diffusion cathode. A Fumasep bipolar membrane in reverse bias supplies protons to the cathode and hydroxide to a Ni foam anode in a recirculated KOH anolyte. Co-ions leak through it: K+ to the cathode, carbonate to the anolyte. That leak, one minus the water dissociation efficiency (WDE), acidifies the anolyte over time.
At this stage the folder holds: - the measured cell configuration; - the WDE series in 1 M KOH (25 to 250 mA/cm2), rebuilt from the raw titration sheets by scripts/adapt_4tu.py; - the measured series of the same 18 runs (cell voltage, CO and H2 Faradaic efficiency, WDE), rebuilt from the raw chronopotentiometry, flow-meter, GC and titration files (experiments/electrochemistry/rbpm-1m-koh.yaml); - the cell balance of the bench cell at 200 mA/cm2 on those measurements (process/cells.yaml); - a labelled cell cross-section; - two pilot skids of 0.100 kg/h CO (#330), each four stacks of seven 100 cm2 cells on a 48 V bus: Skid A on one fill of 1 M KOH sized to reach pH 12 at the end of the campaign, Skid B on 50 L held steady by continuous 5 M KOH dosing, bleed and make-up; their duties, stacks, flowsheet (two trains, two cases), P&IDs, lists, control, layout and the calculation records of the 1,000 h and 10,000 h scenarios, all regenerated by scripts/regen.py.
Every skid number rests on ASSUMED inputs (product duty, recovery, envelope, setpoints) and on the 1 h measurements in fresh 1 M KOH held over the whole campaign by assumption.
The independent reproduction of the published series and model is a separate, held-out benchmark (benchmarks/reproductions/vermaas-rbpm-wde, ADR 0030 and 0032). The LCI and a climate-change screening of both skids per kg CO delivered (#331, part of it; tracker core#136) are in lca/: the unallocated datasets of both designs, reconciled with the duty totals, and the gaps that leave the comparison of the skids open.